Technical specifications

• Ionization method: MALDI with up to 2 kHz laser speed (laser pulses per second)
• Bruker smartbeam-II Laser, 355 nm
• Effective flight tube length: 120 cm (linear mode), 215 cm (reflection mode)
• Mass accuracy ≤ 10 ppm (reflector mode, external calibration)
• Target plates with 96 sample spots

Automation

• not possible

Fields of application

• Absolute molar mass determination of polymers including end group determination, details by arrangement

Primary use

• Polymer chemistry, organic chemistry, inorganic chemistry
• Independent use possible after instruction

Ion sources

• ESI (Electrospray Ionization)
• APCI II (Atmospheric pressure chemical ionization)
• Direct Probe Option APCI II

Automation

• none

Fields of application

• High-resolution mass spectra in the m/z range 40 – 40000
• Ion fragmentation (MSMS coupling)
• Ion mobility analysis

Primary use

• Coordination chemistry, organic chemistry, inorganic chemistry, polymer chemistry
• Service measurements

Sample heads

• BBO (³¹P-¹⁰⁹Ag/¹H) 5 mm
• TBI (¹H/³¹P-¹⁰⁹Ag) 5 mm

Automation

• 60-fold sample changer

Temperature control

• currently not possible

Fields of application

• Hetero-core experiments, ¹H{¹³C/X} experiments with X ≠ ¹⁹F

Primary use

• Inorganic chemistry, coordination chemistry
• Independent use possible after instruction

The utilization of the 500 MHz NMR Sspectrometer can be accessed remotely (TUC internal only for activated users) via the following link:IconNMR 500 MHz

Sample heads

• BBFO SMART (¹H/³¹P – ¹⁴N+¹⁹F) 5 mm
• TBO (³¹P – ¹⁵N, ¹⁹F/¹H) 5 mm

Automation

• 24-fold SampleCase sample changer

Temperature control

• -100°C bis +120°C

Fields of application

• Structure elucidation, investigation at highest field, investigation of dynamic phenomena, NMR titrations, measurements of insensitive nuclei (e.g. 15N), DOSY experiments, 19F-NMR experiments, measurement of small amounts of substance

Primary use

• Organic chemistry, theoretical organic chemistry, polymer chemistry
• Independent use possible after instruction

Sample heads

• BBI (¹H/³¹P-¹⁰⁹Ag) 5 mm (standard sample head)
• DUL (¹³C/¹H) 5 mm
• BBO (³¹P-¹⁰⁹Ag/¹H) 10 mm

Automation

• none

Temperature control

• RT to +120°C

Areas of application

• ¹H-, ¹H-X correlations (e.g. HSQC, HMBC measurements), direct hetero-core NMR conditionally possible, reaction controls, DOSY measurements, structure elucidation
• Education

Primary use

• Polymer chemistry
• Independent use possible after instruction

• Booking of measuring time via exchange calendar:
  room-na62-007@…

Sample heads

• 2,5 mm MAS (¹³C-³¹P/¹H), up to 30 kHz MAS
• 3,2 mm MAS (¹⁵N-³¹P/¹H), up to 20 kHz MAS
• 4,0 mm MAS (⁵⁹Co-³¹P/¹H), up to 13 kHz MAS
• 7,0 mm MAS (¹⁵N-³¹P/¹H), up to 5 kHz MAS
• 7,0 mm MAS (¹⁹⁵Pt-³¹P/¹H), up to 5 kHz MAS

Automation

• none

Temperature control

• RT to +80°C

Fields of application

• Structural characterization of solid samples

Primary use

• Measurements as a service
• Instruction also possible on request

Sample heads

• Dual ¹³C/¹H, 5 mm

Automation

• 24-fold SampleCase sample changer

Temperature control

• RT to +120°C

Fields of application

• ¹H, ¹³C, HSQC, HMBC measurements, reaction controls, structure determination

Primary use

• MAIN employees